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Die meta C–H‐Funktionalisierung durch Ruthenium‐katalysierte σ‐Bindungsaktivierung hat sich als nützliches Werkzeug zum Knüpfen distaler C–C‐Bindungen erwiesen. Aufgrund der begrenzten Anzahl von mechanistischen Studien ist jedoch kein klares Verständnis des Hintergrunds der Regioselektivität und des vollständigen Reaktionsmusters vorhanden. Hier präsentieren wir systematische computerchemische Studien...
Ruthenium‐catalyzed σ‐bond activation‐assisted meta‐C−H functionalization has emerged as a useful tool to forge distal C−C bonds. However, given the limited number of mechanistic studies, a clear understanding of the origin of the site‐selectivity and the complete reaction pattern is not available. Here, we present systematic computational studies on ruthenium‐catalyzed C−H functionalization with...