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Readily available substituted phenols were coupled with pyruvate in buffer solution under atmospheric conditions to afford the corresponding para‐vinylphenol derivatives while releasing only one molecule of CO2 and water as the by‐products. This transformation was achieved by designing a biocatalytic system that combines three biocatalytic steps, namely the CC coupling of phenol and pyruvate in the...
Ungeschützte Phenole werden von W. Kroutil, E. Busto und R. C. Simon in ihrer Zuschrift auf S. 11049 ff. unter Verwendung von Pyruvat selektiv para‐vinyliert. Das Bild veranschaulicht diese Umsetzung ausgehend von einem substituierten Phenol, das auf seinem Weg nach unten an den drei beteiligten Enzymen vorbeikommt, wobei Wasser und CO2 freigesetzt werden (Bild: Verena A. Resch).
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