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Thermoelectric NaxCo2O4/Ag composites were synthesized by citric acid complex (CAC) method and Ag precipitation from CH3COOAg aqueous solution on the NaxCo2O4 powders. Effects of the synthesis process on microstructure and thermoelectric performance of NaxCo2O4/Ag composites were investigated. When the NaxCo2O4 CAC powders were dipped in CH3COOAg aqueous solution and dried, fine Ag particles less...