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In this report, a synergistic combination of L‐arginine and [bmim]Br has been realized for the first time towards step‐economical synthesis of β‐aryl‐β‐sulfanyl esters from aromatic aldehyde, malonate and thiol via cascade thia‐Michael addition reaction on in situ formed unactivated β‐aryl‐α,β‐unsaturated esters (via decarboxylative Knoevenagel reaction) under metal‐and acid/base‐free conditions....
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