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Annähernd stöchiometrische O2‐Mengen werden freigesetzt, wenn ein wässriger Puffer (pH 8), der [RuII(2,2′‐Bipyridin)3], Na2S2O8 und einen Heteromehrkern‐Cyanidkomplex mit Co‐ und Pt‐Ionen als Photosensibilisator, Elektronenakzeptor bzw. Wasseroxidationskatalysator enthält, mit sichtbarem Licht bestrahlt wird. Y. Yamada, S. Fukuzumi et al. konnten in der Zuschrift auf S. 5705 ff. eine Synergie zwischen...
A near‐stoichiometric amount of O2 was evolved as observed in the visible‐light irradiation of an aqueous buffer (pH 8) containing [RuII(2,2′‐bipyridine)3] as a photosensitizer, Na2S2O8 as a sacrificial electron acceptor, and a heteropolynuclear cyanide complex as a water‐oxidation catalyst. The heteropolynuclear cyanide complexes exhibited higher catalytic activity than a polynuclear cyanide complex...
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