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The band-target entropy minimization (BTEM) curve resolution technique has been used to analyze in situ reflection–absorption infrared spectroscopy (RAIRS) data of CO chemisorption on Ni(111) single crystal surfaces. The bilinearity assumption for pRAIRS data, that is, negative logarithm to the base 10 of raw reflectance RAIRS data, was found to be sufficiently valid for the test data. A total of...
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