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In this study, the La–Ni and LaNi5–H systems were thermodynamically reassessed while taking into consideration the La5Ni19 phase. High-resolution X-ray diffraction and differential scanning calorimetry showed that the La5Ni19 phase was formed from the liquid and LaNi5 phases through a peritectic reaction, L+LaNi5→La5Ni19, at 1276K, and existed stably down to the room temperature. The phase equilibrium...
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