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Four precious metals supported on activated carbon are compared as catalysts in the gas-phase hydrodechlorination (HDC) of chloromethanes. The intrinsic activity or turnover frequency (TOF) of the catalysts follows the order Pd/C>Rh/C>Pt/C>Ru/C in the HDC of dichloromethane (DCM) while the sequence Pd/C>Pt/C>Rh/C>Ru/C was found for the HDC of chloroform (TCM). High selectivities...
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