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A microscopic phase-field method was employed to study the evolution in microstructure of Ni-Al-V alloys during the ordering process. The FCC->L1 2 /D0 22 phase transition proceeds with an intermediate transient L1 0 /L1 0 (M=1) phase at the critical Al level where the two phases co-exist. Additionally, L1 2 may act as a transient phase of D0 2 ...
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