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BN‐butafulvenes, mono‐BN isosteres of butafulvene and highly strained isomers of azaborines and B‐amino boroles, have been synthesized via hydrolysis of the urana‐borabicyclic complexes obtained from the reactions of bis(alkynyl)boranes with an uranacyclopropene complex. Their 4‐dimethylaminopyridine (DMAP) adducts can further isomerize to 1,2,4,6‐multisubstituted BN‐9,1‐naphthalenes. Both NMR reaction...
BN‐Butafulvene, Mono‐BN‐Isostere von Butafulven und hochgespannte Isomere von Azaborinen und B‐Aminoborolen, wurden durch Hydrolyse der Urana‐Borabicyclus‐Komplexe synthetisiert, die aus der Reaktion von Bis(alkinyl)boranen mit einem Uranacyclopropen‐Komplex stammen. Ihre 4‐Dimethylaminopyridin (DMAP)‐Addukte können weiter zu 1,2,4,6‐multisubstituierten BN‐9,1‐Naphthalinen isomerisieren. Sowohl die...
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