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The kinetics and mechanisms of the reduction of NO3− in solution to NH3 by 1.5μm diameter zero-valent iron (ZVI1.5) particles has been examined. The effects of initial pH, ZVI1.5 particle concentration and initial NO3− concentration were also investigated. Results indicate that denitrification by ZVI1.5 is primarily a pH-dependent, surface-mediated process. At an initial ZVI1.5 concentrations of 0...
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