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Adsorption of carbon monoxide on a nanosized apex facet of a [111]-oriented Pt field emitter tip was studied under high electrostatic field conditions (15–20V/nm) by field ion appearance energy spectroscopy (FIAES). Weakly bound highly mobile CO species have been detected and their possible role in surface reactions such as CO oxidation on Pt was elucidated.The FIAES results are compared with those...
In this short review we present few selected sections of our own work on the catalytic reactions as studied on a nanoscale using the field emission and field ion microscopies (FEM/FIM) and the corresponding probe-hole techniques: magnetic field ion mass separation combined with the field ion appearance energy spectroscopy (FIAES) and an atom probe with a Wien-filter ion mass selection combined with...
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