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Schwermetallcorrole sind von großem Interesse als optische Sensoren, Nah‐IR‐Farbstoffe, Leuchtstoffe, OLEDs und Tumortherapeutika, allerdings ist die Insertion von 5d‐Metallen in Corrole schwierig. A. Ghosh et al. beschreiben in ihrer Zuschrift auf S. 14639 ff. die oxidative Metallierung von meso‐Triarylcorrolen mit [Os3(CO)12]/NaN3 als Route zu Nitridoosmium(VI)‐corrolen. Diese Komplexe weisen ausgeprägt...
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