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Ni-based metallic glasses containing no metalloids are developed in Ni-Zr-Nb-Al alloy system. A partial replacement of Zr with Nb in Ni-Zr-Al alloys significantly enhances the glass-forming ability (GFA) and enlarges the undercooled liquid region during continuous heating of glassy ribbons. A quaternary Ni-Zr-Nb-Al metallic glasses exhibit large undercooled liquid region (>50 K), indicating high...
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