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We report on the influence of the length of thiol alkyl chains used to coat silver sulfide particles on the self-organization of nanoparticles in monolayers. The variation of the average distance between particles with the length of the thio derivatives alkyl chain is derived from direct measurements of TEM patterns.
The influence of the substrate on the morphology of 2D and 3D superlattices made of 5.8 nm silver sulfide nanocrystals coated with dodecanethiol is reported. Two substrates, highly oriented pyrolytic graphite (HOPG) and molybdenum disulfide (MoS 2 ), are used. Self-assemblies of nanocrystals are characterized with scanning electron microscopy (SEM), transmission electron microscopy (TEM) and...
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