The Infona portal uses cookies, i.e. strings of text saved by a browser on the user's device. The portal can access those files and use them to remember the user's data, such as their chosen settings (screen view, interface language, etc.), or their login data. By using the Infona portal the user accepts automatic saving and using this information for portal operation purposes. More information on the subject can be found in the Privacy Policy and Terms of Service. By closing this window the user confirms that they have read the information on cookie usage, and they accept the privacy policy and the way cookies are used by the portal. You can change the cookie settings in your browser.
Der richtige Dreh: Nicht oft wird nach experimentellen Belegen für relativistische Effekte auf den Tensor der chemischen Verschiebung in der Festkörper‐NMR‐Spektroskopie gesucht. 29Si‐MAS‐NMR‐spektroskopische Messungen mit langsamer Rotation (MAS=Rotation im magischen Winkel) an der Triade [ClTM(μ‐mt)4SiCl] (TM=Pt, Pd, Ni; mt=2‐Mercapto‐1‐methylimidazolid) zeigten, dass die Schweratom‐Spin‐Bahn‐Kopplung...
SO what? Spectral features caused by relativistic effects on chemical shift tensors are not always looked for in solid‐state NMR spectroscopy. Slow‐rotation 29Si magic‐angle spinning (MAS) NMR measurements on the triad [ClTM(μ‐mt)4SiCl] (TM=Pt, Pd, Ni; mt=2‐mercapto‐1‐methylimidazolide) reveal that heavy‐atom spin–orbit (SO) coupling has a dramatic impact on the 29Si NMR spectral peak shape.
Set the date range to filter the displayed results. You can set a starting date, ending date or both. You can enter the dates manually or choose them from the calendar.