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The inner structure of a pressure‐sensitive adhesive (PSA) is investigated at the surface as well as at the buried adhesive–adherent interface. Time‐of‐flight grazing‐incidence small‐angle neutron scattering (TOF‐GISANS) is used to obtain depth‐resolved structural information about the statistical copolymer poly(ethylhexylacrylate‐stat‐d‐methylmethacrylate), which represents a well studied model PSA...
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