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Three new copper azide compounds, [Cu5(N3)10(N‐2AE‐1,3‐DAP)2] (I), [Cu5(N3)10(N‐3AP‐1,3‐DAP)2] (II), and [Cu7(N3)16(1‐(2‐AE)PIP‐H)2] (III) {where N‐2AE‐1,3‐DAP = N‐2‐aminoethyl‐1,3‐propanediamine, N‐3AP‐1,3‐DAP = N‐3‐aminopropyl‐1,3‐propanediamine, and 1‐(2‐AE)PIP = 1‐(2‐aminoethyl)piperazine} have been prepared by employing aliphatic amine molecules as coordination blocking amines. All the structures...
A method based on finite temperature canonical ensemble Monte Carlo (MC) simulation of sorbates confined in the micropores of zeolites is proposed for the estimation of pore volumes. The method consists of carrying out Monte Carlo simulation to obtain the total potential energy of interaction, U tot , as a function of N, the number of sorbates confined within the pores of the...
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