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By using Tf 2 O as a catalyst, we have developed a protocol for the preparation of various dibenzo[a,d]cycloheptene cores via Friedel–Crafts alkylation. Using this method as the key step, we also present concise and useful routes to synthesize the natural products Diptoindonesin D, Pauciflorial F, and (±)-Ampelopsin B. Notably, this process exhibited following very attractive features: (i)...
This chapter contains sections titled:
Introduction
Silver‐Mediated Oxidation of Alkanes
Silver‐Mediated Oxidation of Alkenes
Silver‐Mediated Oxidation of Alkynes
Silver‐Mediated Oxidation of Alcohols, Aldehydes, Imines, and Decarboxylation
Silver‐Mediated Oxidation with the Formation of CN Bonds
Silver‐Mediated Carbene and Silylene Transfers
Miscellaneous Silver‐Mediated Oxidation Reactionsconclusion...
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