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A reaction network consisting of dimerization, dehydration and isomerization of fructose for the synthesis of 5-hydroxymethylfurfural (HMF) is devised. Difructose anhydride (DFA) isomers were identified as the primary reaction products and reaction intermediates for HMF formation. The effect of functionalization method on the catalytic performance of sulfonated-ordered MCM-41 or disordered mesoporous...
The catalytic reaction of the melt transesterification of diphenyl carbonate (DPC) and bisphenol-A (BPA) is investigated theoretically. A reaction mechanism based on the nucleophilic substitution on the carbonyl group of reactants is proposed for the description of the kinetic behavior of the reaction under consideration. Previous models are extended so that the kinetic model derived is not only more...
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