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Ein Licht im Dunkeln reicht aus, um zwischen der konformativ flexiblen und der gestreckten Form eines selbstorganisierten Koordinationskäfigs hin‐ und herzuschalten, der aus zwei quadratisch‐planar koordinierten PdII‐Ionen und vier Liganden mit photochromem Dithienylethen‐Grundgerüst besteht. Die lichtgetriebene Umwandlung verläuft sauber und reversibel und ermöglicht die Verkapselung und Freisetzung...
A guiding light is sufficient to switch back and forth between the flexible and the stretched, rigid form of a self‐assembled coordination cage based on two square‐planar‐coordinated PdII ions and four ligands with a photochromic dithienylethene (DTE) backbone. The light‐driven interconversion is clean and reversible and allows to control the encapsulation and release of the guest [B12F12]2−.
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