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A new electron‐deficient unit with a fused 5‐membered heterocyclic ring was developed by replacing a cyclopenta‐1,3‐diene from electron‐rich donor indacenodithiophene (IDT) with a cyclohepta‐4,6‐diene‐1,3‐diimde unit. The imide bridge endows dithienylbenzenebisimide (BBI) with a fixed planar configuration and low energy levels for both the highest occupied molecular orbital (HOMO; −6.24 eV) and the...
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