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An organocatalytic approach to living and condensation polymerization using N-heterocyclic carbenes as nucleophilic catalysts is detailed. The N-heterocyclic carbene catalyst platform is extremely versatile with the nature of the substituents having a pronounced effect upon catalyst stability and activity towards different substrates. Rapid screening of libraries of catalysts provided a basic understanding...
Examination of the chemistry of sterically crowded (C 5 Me 4 R) 3 Ln complexes has provided access to a series of [(C 5 Me 4 R) 2 Ln] 2 (μ-O) complexes: [(C 5 Me 5 ) 2 La] 2 (μ-O), [(C 5 Me 5 ) 2 Nd(NC 5 H 4 NC 4 H 8 )] 2 (μ-O), [(C 5 Me ...
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