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Small molecule solar cells (SMSCs) lag a long way behind polymer solar cells. A key limit is the less controllable morphology of small molecule materials, which can be aggravated when incorporating anisotropic nonfullerene acceptors. To fine‐tune the blending morphology within SMSCs, a π‐conjunction curtailing design is applied, which produces a efficient benzodithionopyran‐cored molecular acceptor...
Nonfullerene polymer solar cells develop quickly. However, nonfullerene small‐molecule solar cells (NF‐SMSCs) still show relatively inferior performance, attributing to the lack of comprehensive understanding of the structure–performance relationship. To address this issue, two isomeric small‐molecule acceptors, NBDTP‐Fout and NBDTP‐Fin, with varied oxygen position in the benzodi(thienopyran) (BDTP)...
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