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The roles that ionic liquids (ILs) can play as extractants, intermediate solvents, mediators and desorption solvents in liquid-phase and solid-phase microextraction (SPME) provide the topic of this review. We emphasize the added value of using ILs in single-drop microextraction, hollow-fiber-based liquid-phase microextraction, dispersive liquid-liquid microextraction, and in-fiber and in-tube SPME,...
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