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Die Kohlenmonoxid‐Fixierung …… durch ionische Flüssigkeiten mit Carbanion‐Motiven ist das Thema der Zuschrift von D. J. Tao, D. Jiang, S. Dai et al. auf S. 6947 ff. Dank ihrer Supernukleophilie können die ionischen Flüssigkeiten CO effizient absorbieren, und eine chemische Wechselwirkung über die C‐Position des Carbanions bildet die Grundlage für die hohe CO‐Kapazität (bis 0.046 mol mol−1) unter Umgebungsbedingungen...
A novel method for the highly efficient and reversible capture of CO in carbanion‐functionalized ionic liquids (ILs) by a C‐site interaction is reported. Because of its supernucleophilicity, the carbanion in ILs could absorb CO efficiently. As a result, a relatively high absorption capacity for CO (up to 0.046 mol mol−1) was achieved under ambient conditions, compared with CO solubility in a commonly...
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