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Stable Pd(0) nanoparticles were prepared at room temperature in 1,4-dioxane from PdCl 2 using N,N′-bis(4-methoxyphenyl)-(1,1′-binaphthyl)-4,4′-diamine (naphthidine) as reducing and stabilizing agent. This procedure resulted in Pd(0) particles possessing an average diameter of ca. 25nm stabilized against aggregation due to a barrier of the naphthidine di(radical cation) Napht 2.2+ ...
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