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A self-assembled monolayer of ferrocene-capped alkanethiols is produced in two stable oxidation states of Fe (Fe 2+ and Fe 3+ ). These oxidation states are detected with sub-monolayer sensitivity by the fine structure of the Fe2p absorption edge. The native Fe 2+ ferrocene layer is converted chemically to Fe 3+ , and the Fe 3+ layer can be transformed back to...
This paper reports an investigation of the influence of interfacial hydrogen bonding on the orientations of liquid crystals at surfaces. The orientations of 10 liquid crystals were examined on carboxylic acid- or methyl-terminated self-assembled monolayers (SAMs) supported on obliquely deposited gold films. The mesogens comprising the liquid crystals each possessed different hydrogen bond acceptors...
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