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The bis(cyclopentadienyl) complexes [Cp 2 Ti(dca)] 2 O and Cp 2 V(dca) 2 (dca=dicyanamide) have been prepared by reaction of sodium dicyanamide with aqueous solution of titanocene dichloride and vanadocene dichloride, respectively. The X-ray structure analyses of both complexes confirmed monodentate coordination of dicyanamide ligand through the terminal nitrogen atom...
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