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Raman spectra of 1,1-difluoro-1-silacyclohexane as a liquid, and as a solid at 78K were recorded and depolarization data obtained. The infrared spectra of the vapour, liquid and amorphous and crystalline solids have been studied. In the low temperature IR and Raman spectra eight and three bands, respectively, were shifted a few cm −1 when the sample crystallized. No bands vanished after crystallization...
Infrared spectra of 3,3,3-trifluoropropyltrichlorosilane (CF 3 CH 2 CH 2 SiCl 3 ) were obtained in the vapour, amorphous and crystalline solid phases in the range 4000–50cm −1 . Additional spectra in argon matrices at 5.0K were recorded before and after annealing to 20–36K. Raman spectra of the compound as a liquid were recorded at various temperatures between...
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