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A new redox system, poly(1,4-phenylene-1,2,4-dithiazol-3′,5′-yl) (PPDTA), is presented as a cathode material for high-capacity lithium secondary batteries. This polymer, composed of 1,2,4-dithiazolium ring and benzene, is synthesized by a cyclooxidative reaction of aromatic thioamides with organic oxidizers. The advantages of this system are: (1) high theoretical charge density; (2) fast redox rate;...
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