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Product detection studies of CN reactions with ethene and propene are conducted at room temperature (4Torr, 533.3Pa) using multiplexed time-resolved mass spectrometry with tunable synchrotron photoionization. Photoionization efficiency curves, i.e., the ion signal as a function of photon energy, are used to determine the products and distinguish isomers. Both reactions proceed predominantly via CN...
The kinetics of the reactions of C 2 H radical with ethane (k 1 ), propane (k 2 ), and n-butane (k 3 ) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C 2 H decay profiles in the presence of both the alkane reactant and O 2 are monitored...
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