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A new series of θ-type BETS salts have been prepared and the crystal structure analyses and the electrical resistivity measurements have been carried out. θ-BETS 2 MM′(SCN) 4 [MM′=RbCo, RbZn, CsCo, CsZn]are isostructural to ET analogues. The metal insulator transition occurs at 25 Kfor θ-RbM′, whereas the metallic behaviors down to 2K have been observed for θ-CsM′ and θBETS 2 ...
The preparation and characterization of organic-inorganic molecule-based systems in which conduction electrons coexist with localized moments is reported. These systems comprise (i) charge transfer salts of organic donors, such as BETS bis(ethylenedithio)tetraselena), and paramagnetic inorganic anions, such as [MX 4 ] - , [M 2 X 6 ] 2- with M = Fe, Cu,...
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