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Cobalt(II) chloro complexation has been studied by titration calorimetry and spectrophotometry in solvent mixtures of N-methylformamide (NMF) and N,N-dimethylformamide (DMF). It revealed that a series of mononuclear CoClnn(2–n)+ (n=1–4) complexes are formed in the mixtures of NMF mole fraction xNMF=0.05 and 0.25, and the CoCl+, CoCl3– and CoCl42– complexes in the mixture of xNMF=0.5, and their...
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