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The potential curves for the dissociation of dodecane cation are calculated in order to discuss the indirect mechanism of metastable-atom-stimulated desorption of CH x+ from dodecanethiolate self-assembled monolayers. A single excitation configuration interaction method is used for drawing up the potential diagrams in two different reaction coordinates: CH and CC. The potential barrier...
By exposure to a metastable helium beam, latent images of the patterns were formed in the heptanethiol (HT) self-assembled monolayer (SAM) resists on Au(111) films, and then the patterns were transferred to the underlying gold films by wet chemical etching. Negative patterns, as well as positive patterns with lower doses, were fabricated with higher exposures to a metastable-atom beam. The smallest...
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