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Die 5d‐Rumpfelektronen von Hg …︁ …︁ werden unter hohem Druck aktiv und beteiligen sich an chemischen Bindungen. In ihrer Zuschrift auf S. 9412 ff. zeigen M.‐S. Miao und Mitarbeiter mithilfe von First‐Principles‐Rechnungen, dass die Verbindungen HgF4 und HgF3 unter hohem Druck stabil sein können. HgF4 bildet Molekülkristalle aus quadratisch‐planaren HgF4‐Molekülen, während HgF3 ein unendlicher Feststoff...
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