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Surface organometallic chemistry (SOMC) represents a unique synthetic platform for the preparation of model heterogeneous catalysts resembling those broadly applied in industry. SOMC techniques usually rely on the grafting of tailored molecular precursors onto the surface OH groups of oxide supports. The development of such precursors and the understanding of their reactivity with the supports are...
Propane dehydrogenation is an important field of research due to an increasing world‐wide demand of propene while classical production routes through naphtha cracking are in decline. In that context, silica‐supported Ga(III) sites, synthesized from surface organometallic chemistry principles, show high selectivity and stability in the propane dehydrogenation reaction. This performance is in significant...
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