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Graphene‐based electrodes have recently gained popularity due to their superior electrochemical properties. However, the exact mechanisms of electrochemical activity are not yet understood. Here, we present data from NADH oxidation and ferri/ferrocyanide redox probe experiments to demonstrate that both (i) the porosity of the graphene electrodes, as effected by the packing morphology, and (ii) the...
An ultra-thin self-supporting Pt-foil with a thickness of 300nm and 4mm diameter has a heat capacity of only 10μJ/K. Thus, even small amounts of heat deposited within the thin metal foil cause a significant temperature increase. During the adsorption of, for example, CO heat in the order of 30μJ/ML is released into the metal. If the rim of a Pt(110) single crystal foil is rigidly mounted on a substrate,...
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