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3-(4-(1H-Benzo[d]imidazol-1-yl)-4-methoxyphenyl)-1-phenylprop-2-en-1-one (L1, 1) and its Mn(II) complex, [Mn(L1)2(SCN)2]∞ (2), were synthesized and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction. The Mn(II) ion in 2 is six-coordinated to four nitrogen atoms of two L1 ligands, two SCN-ligands, and two oxygen atoms of other two L1 ligands...
The synthesis and characterization of two new halfsandwich mononuclear nickel(II) complexes with the scorpionate ligands, [k3-N, N',N''-Tpt-Bu, MeNiI] (1) and [k3-N,N',N''-Tpt-Bu, MeNiNO3] (2), are reported. These complexes have been fully characterized by elemental analyses and infrared spectra. Their molecular structures were determined by single crystal X-ray diffraction. The nickel(II)...
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