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Following the modular template synthesis using isonitriles, new unsymmetrically substituted five‐membered saturated N‐heterocyclic carbene (NHC) and N‐heterocyclic oxo‐carbene (NHOC) gold(I) complexes were prepared. With these species and already reported complexes, a detailed study concerning the catalytic activities of the complex classes available by the isonitrile route was conducted. The catalytic...
The front cover image, provided by Stephen Hashmi and co‐workers, illustrates the results of their work on the synthesis and catalytic activity of saturated and unsaturated NHC as well as NHOC gold(I) complexes. The catalytic activity is strongly influenced by the type of ligand and by side‐chain ring size. For the furane‐yne cyclization the saturated NHC bearing a 15‐membered ring as a side‐chain...
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