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The time dependence on analyte concentration at the surface of a flow-by potentiometric sensor in the flow-injection analysis was investigated theoretically. The relationships between the properties of response and experimental parameters, such as the sample volume and the distance between the injection point and the sensor, was calculated by finite difference numerical simulation.
The electrocatalytic activity of various metal hexacyanoferrates (Mhcfs) (i) immobilized on graphite electrodes, and (ii) as components of a composite electrode was investigated with respect to the reduction of hydrogen peroxide. The flow-through working electrode was a thin layer consisting of a composite of Mhcf, graphite, and polymethylmetacrylate (PMMA) as a binder, sandwiched between two Plexiglas...
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