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Three triazine‐based dendrons (1 a–c) were successfully prepared in 70–83 % yields. These newly prepared dendrons are found to be liquid crystalline (LC). Computational investigations on molecular conformations and dipoles of triazine‐based dendrons reveal that the substituent on the central triazine unit interrupts strong dipole or H‐bond interactions to avoid dimeric formation. The obtained dendrons,...
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