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We report here the first artificial fabrication of riomarinaite (Bi(OH)SO 4 ⋅H 2 O), a new mineral found in 2000 in Italy. Urchin-like Bi(OH)SO 4 ⋅H 2 O lump-assembled films were obtained by potentiostatic anodization of bismuth electrodes in H 2 SO 4 solution. The dissolution–precipitation mechanism can account for the formation of Bi(OH)SO 4 ...
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