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Auger and core-level photoemission from thin NiO films deposited on an MgO(100) substrate are studied by XAES and XPS, respectively. A detailed analysis of the Ni 2p 3/2 main line and Ni L 3 VV for submonolayer coverages allows us to give a new assignement to the different spectral features. In terms of a cluster model, the high binding-energy component of the Ni 2p 3...