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A series of manganese(II) and (III) complexes of tridentate NN O donor set Schiff base ligands has been prepared by the electrochemical oxidation of a manganese anode in an acetonitrile solution of the Schiff bases (R-salaepH). These complexes are found to be of the form [Mn(R-salaep) 2 ] and [Mn(R-salaep) 2 ]ClO 4 . The single crystal X-ray structure of bis{[2-(2-pyridyl)ethyl]-iminomethyl-5-nitro-phenoxy}manganese(II)...
A series of manganese(II) complexes of bidentate NO donor set Schiff base ligands, together with corresponding mixed complexes containing 1,10-phenanthroline (phen), have been prepared by the electrochemical oxidation of a manganese anode in acetonitrile solutions of the Schiff bases (HL) and phen. The complexes formed are found to be of the form [Mn(L) 2 ] nH 2 O and [Mn(L) ...