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Two new Ru(II) complexes containing tris(2-pyridylmethyl)amine was synthesised by reacting [RuCl2 (EPh3)3] E = P, As with TPA.3HClO4 in 1:1 ratio. The new complexes were characterized by various spectroscopic (IR, UV–Vis and NMR) techniques and the structure of the complexes was confirmed by X-ray crystallography. Crystallographic studies of the complexes 1 and 2 revealed the octahedral geometry around...
New palladium(II) binuclear complexes (1–4) of the type [Pd2(Msal-Rtsc)2(μ-dppm)] (R=H or CH3 or C2H5 or C6H5) were prepared and characterised by using various spectro analytical techniques. The true coordinating nature of the ligands in the complexes was confirmed by X-ray crystallographic studies. From the X-ray crystallographic analysis, it is found that the ligands [H2L1–H2L4] were bound to metal...
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