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A kind of new fused‐ring electron acceptor, IDT‐OB, bearing asymmetric side chains, is synthesized for high‐efficiency thick‐film organic solar cells. The introduction of asymmetric side chains can increase the solubility of acceptor molecules, enable the acceptor molecules to pack closely in a dislocated way, and form favorable phase separation when blended with PBDB‐T. As expected, PBDB‐T:IDT‐OB‐based...
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