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In situ Attenuated Total reflectance infrared (ATR IR) spectroscopy is used to study the interaction between ethanol vapour and oxidised nanodiamond (ND) surfaces. On initial exposure an amorphous multilayer of adsorbed ethanol is observed, but over ca. 30min a loss in intensity of ν(OH) and δ(OH) bands indicates a preferential binding of the ethanol –OH with the ND surface. Other spectral changes...