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Pt(PH 3 ) 2 -catalyzed hydrosilylation of ethylene involving cis-trans isomerization of PtH(SiH 3 )(PH 3 ) 2 was theoretically investigated with ab initio MO/MP2-MP4SDQ and CCD methods. The cis-trans isomerization via Berry's pseudo-rotation mechanism occurs with an activation barrier (E a ) of 28 kcal/mol when promoted by PH 3 and with E ...
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