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Recently, azanone (HNO), which is the protonated one-electron reduction product of ·NO, has gained considerable attention due to its unique pharmacological effects. Although there has been much progress in understanding HNO biology and chemistry, it remains the most elusive reactive nitrogen species. Herein, we applied the competition kinetics method, based on two parallel HNO reactions with the different...
Nitroxyl (HNO, IUPAC name azanone), being formally the protonated product of one-electron reduction of nitric oxide (NO), is an elusive reactive nitrogen species possessing interesting biological chemistry and high pharmacological importance.1,2 Contrary to nitric oxide, HNO is a strong electrophile highly reactive towards nucleophiles.Here, we present the study on the kinetics of HNO reaction with...
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